Preheat the oven to 350 degrees F (175 degrees C). Coat a baking dish with cooking spray.

Coat a large skillet with cooking spray; heat over medium heat. Season pork chops with salt and black pepper; add chops to the hot skillet. Cook until browned, about 5 minutes per side.

Meanwhile, combine brown sugar and honey in a microwave-safe bowl. Microwave on high until brown sugar has softened or melted, about 20 seconds. Stir until glaze is smooth.

Transfer chops to the prepared baking dish; spread ½ of the honey glaze evenly over the top.

Bake, uncovered, in the preheated oven for 15 minutes. Flip chops; spread remaining honey glaze over the top. Continue baking until pork is no longer pink in the centers, 15 to 20 minutes more. An instant-read thermometer inserted into the centers should read 145 degrees F (63 degrees C).